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\n1 \u73b0\u5c06\u5382\u5bb6\u63d0\u4f9b\u7684 N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\u68c0\u6d4b\u65b9\u6cd5\u7b80\u8ff0\u5982\u4e0b\uff1a\u8be5\u65b9\u6cd5\u4e3a\u76d0\u9178-\u9187\u6807\u51c6\u6ef4\u5b9a\u6eb6\u6db2\u6ef4\u5b9a\u6cd5
\n1.1 \u8bd5\u5242
\n\u4e59\u9178\u9150\uff08\u5206\u6790\u7eaf\uff09
\n\u4e59\u4e8c\u9187+\u5f02\u4e19\u9187\uff081:1\uff09
\n\u76d0\u9178-\u9187\u6807\u51c6\u6eb6\u6db2\uff080.5mol\/L\uff09
\n\u7532\u57fa\u9ec4-\u6b21\u7532\u57fa\u84dd\u6307\u793a\u5242
\n1.2 \u68c0\u9a8c\u6b65\u9aa4
\n\u79f0\u53d6 1.0-1.5g \u6837\u54c1\uff08\u7cbe\u786e\u5230 0.001g\uff09\u4e8e 150ml \u9525\u5f62\u74f6\u4e2d\uff0c\u52a0 10ml \u4e59\u9178\u9150\uff0c30ml \u4e59\u4e8c\u9187+\u5f02\u4e19\u9187\uff081:1\uff09\u518d\u52a0 3-4 \u6ef4\u7532\u57fa\u9ec4-\u6b21\u7532\u57fa\u84dd\u6307\u793a\u5242\uff0c\u7528\u76d0\u9178-\u9187\u6807\u51c6\u6eb6\u6db2\uff080.5mol\/L\uff09\u6ef4\u5b9a\u5448\u7ea2\u68d5\u8272\u4e3a\u7ec8\u70b9\u3002
\n2 \u6539\u8fdb\u7684 N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\u68c0\u6d4b\u65b9\u6cd5
\n2.1 \u65b9\u6cd5\u539f\u7406
\n\u672c\u65b9\u6cd5\u4e3a\u6c14\u76f8\u8272\u8c31\u6cd5\uff0c\u91c7\u7528 DB-WAX \u6bdb\u7ec6\u67f1\uff0c\u5728\u89c4\u5b9a\u7684\u5de5\u4f5c\u6761\u4ef6\u4e0b\uff0c\u7528\u6c22\u706b\u7130\u79bb\u5b50\u68c0\u6d4b\u5668\u68c0\u6d4b\uff0c\u6d4b\u5b9a\u5176\u6821\u6b63\u56e0\u5b50\uff0c\u6839\u636e\u5916\u6807\u6cd5\u5b9a\u91cf\u5206\u6790N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\u7684\u542b\u91cf\u3002
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\n2.2.2 \u8bb0\u5f55\u7cfb\u7edf
\n\u4e0e Agilent7890A \u578b\u4eea\u5668\u5339\u914d\u7684\u5de5\u4f5c\u7ad9
\n2.2.3 \u8272\u8c31\u67f1
\nDB-WAX \u6bdb\u7ec6\u67f1\uff1a\u67f1\u957f\uff1a30m\uff0c\u67f1\u5185\u5f84\uff1a0.45mm,\u6db2\u819c\u539a\u5ea6\uff1a0.85\u03bcm
\n2.2.4 \u8fdb\u6837\u8bbe\u5907
\n\u6ce8\u6837\u5668\uff1a10\u03bcL\uff0c\u914d\u81ea\u52a8\u8fdb\u6837\u5668\uff08\u53ef\u624b\u52a8\u8fdb\u6837\uff09
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\n\uff081\uff09\u6c22\u6c14\uff1a\u4f53\u79ef\u5206\u6570\u4e0d\u4f4e\u4e8e 99%\uff0c\u7ecf\u7845\u80f6\u4e0e\u5206\u5b50\u7b5b\u5e72\u71e5\u3001\u51c0\u5316\u3002
\n\uff082\uff09\u6c2e\u6c14\uff1a\u4f53\u79ef\u5206\u6570\u4e0d\u4f4e\u4e8e 99.99%\uff0c\u7ecf\u7845\u80f6\u4e0e\u5206\u5b50\u7b5b\u5e72\u71e5\u3001\u51c0\u5316\u3002
\n\uff083\uff09\u7a7a\u6c14\uff1a\u7ecf\u7845\u80f6\u4e0e\u5206\u5b50\u7b5b\u5e72\u71e5\u3001\u51c0\u5316\u3002
\n\uff084\uff09N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\uff1a\u5206\u6790\u7eaf
\n\uff085\uff09\u84b8\u998f\u6c34
\n2.4 \u8272\u8c31\u6761\u4ef6
\n\u6c22\u6c14\u6d41\u91cf\uff1a30ml\/min\uff1b\u7a7a\u6c14\u6d41\u91cf\uff1a400ml\/min\uff1b\u5c3e\u5439\u6d41\u91cf\uff08\u6c2e\u6c14\uff09\uff1a25ml\/
\nmin\uff1b
\n\u67f1\u7bb1\u6e29\u5ea6\uff1a190\u2103,\u4fdd\u6301 20 \u5206\u949f\uff1b
\n\u8fdb\u6837\u53e3\u6e29\u5ea6:350\u2103\uff1b
\n\u6c22\u706b\u7130\u68c0\u6d4b\u5668\u6e29\u5ea6\uff1a350\u2103\uff1b
\n\u8fdb\u6837\u91cf\uff1a0.2\u03bcL\uff1b\u5206\u6d41\u6bd4\uff1a10:1
\n2.5 \u64cd\u4f5c\u6b65\u9aa4
\n\uff081\uff09\u6807\u51c6\u66f2\u7ebf\u7684\u7ed8\u5236
\n\u5206\u522b\u79fb\u53d6\u5206\u6790\u7eaf MDEA \u914d\u5236\u6210 35%\u300138%\u300141%\u300145%\u300147%\u300149%\u6d53\u5ea6\u7684 N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\u6c34\u6eb6\u6db2\uff0c\u5206\u522b\u6ce8\u5165 6 \u53ea\u81ea\u52a8\u8fdb\u6837\u5c0f\u74f6\u4e2d\uff0c\u542f\u52a8\u6c14\u76f8\u8272\u8c31\u4eea\uff0c\u6253\u5f00\u5de5\u4f5c\u7ad9\uff0c\u6309\u7167 2.3 \u8272\u8c31\u6761\u4ef6\u8bbe\u5b9a\u4eea\u5668\uff0c\u7528\u81ea\u52a8\u8fdb\u6837\u5668\u8fdb 0.2?L\u6807\u51c6\u6837\u54c1\uff0c\u542f\u52a8\u4eea\u5668\uff0c\u5e26\u6eb6\u6db2\u51fa\u5cf0\u5b8c\u6bd5\u540e\u505c\u6b62\uff0c\u91c7\u7528\u6c22\u706b\u7130\u79bb\u5b50\u6cd5\u6d4b\u5b9aMDEA \u7684\u8272\u8c31\u5cf0\u9762\u79ef\uff0c\u5229\u7528\u591a\u70b9\u5916\u6807\u6cd5\u8ba1\u7b97\u6821\u6b63\u56e0\u5b50\uff0c\u7136\u540e\u7ed8\u5236\u6807\u51c6\u5de5\u4f5c\u66f2\u7ebf\uff0c\u7531\u4e8e\u5177\u6709\u8272\u8c31\u5de5\u4f5c\u7ad9\uff0c\u66f2\u7ebf\u5728\u3002\u6821\u6b63\u56e0\u5b50\u4e0b\u5f0f\u8ba1\u7b97\uff1a
\nfi=Ei\/Ai
\n\u5f0f\u4e2d\uff1afi-\u6821\u6b63\u56e0\u5b50
\nEi-\u7b2c i \u4e2a\u6807\u51c6\u6eb6\u6db2 MDEA \u7684\u6d53\u5ea6
\nAi-\u7b2c i \u4e2a\u6807\u51c6\u6eb6\u6db2 MDEA \u7684\u5cf0\u9762\u79ef
\n\uff082\uff09\u8bd5\u6837\u7684\u6d4b\u5b9a
\n\u5c06 N-\u7532\u57fa\u4e8c\u4e59\u9187\u80fa\u6837\u54c1\u76f4\u63a5\u7f6e\u4e8e\u81ea\u52a8\u8fdb\u6837\u5c0f\u74f6\u4e2d\uff0c\u542f\u52a8\u6c14\u76f8\u8272\u8c31\u4eea\uff0c\u6253\u5f00\u5de5\u4f5c\u7ad9\uff0c\u91c7\u7528\u4e0a\u8ff0\u76f8\u540c\u8272\u8c31\u6761\u4ef6\u6d4b\u5b9a\u5176\u76f8\u5e94\u503c\uff0c\u4ece\u6807\u51c6\u66f2\u7ebf\u67e5\u5f97 MDEA \u7684\u51c6\u786e\u6d53\u5ea6\u3002\u8c31\u56fe\u5982\u4e0b\uff1a
\n2.5 \u7ed3\u679c\u8868\u8ff0
\n\u5728\u8272\u8c31\u5de5\u4f5c\u6761\u4ef6\u4e0b\u8fdb\u6837\u5206\u6790\uff0c\u5206\u6790\u5b8c\u6bd5\u540e\uff0c\u79ef\u5206\u4eea\u76f4\u63a5\u7ed9\u51fa\u5b9a\u91cf\u7ed3
\n\u679c\u3002
\n2.6 \u7cbe\u5bc6\u5ea6\u8bd5\u9a8c\u5bf9\u6d53\u5ea6\u4e3a 45%\u7684\u6807\u51c6\u6eb6\u6db2\u5e73\u884c\u8fdb\u6837 3 \u6b21\uff0c\u5728 2.3 \u8272\u8c31\u6761\u4ef6\u8fdb\u884c\u6d4b\u5b9a\uff0c\u6d4b\u5b9a\u7ed3\u679c\u5217\u4e8e\u4e0b\u8868\uff1a
\n3 \u8ba8\u8bba
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